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PEI Injection Molding2024-11-23T12:35:28+00:00

PEI Injection Molding

PEI (Polyetherimide) is a premium thermoplastic widely utilized in injection molding for its exceptional mechanical, thermal, and chemical performance.

What is PEI?

PEI (Polyetherimide) is a durable, high-performance plastic valued for its remarkable heat resistance, strength, and chemical stability. It excels in maintaining mechanical and electrical properties under high temperatures, tolerating up to 200°C short-term and 180°C long-term. These qualities make it a preferred material for applications in aerospace, automotive, electronics, and medical industries.

Its molecular structure, comprising polyether and imide groups, contributes to its robust performance. The imide groups enhance its resistance to heat, chemicals, and electricity, while the polyether groups provide toughness and impact resistance.

What are the characteristics of Polyetherimide (PEI)?

PEI (Polyetherimide) offers a range of impressive qualities, making it suitable for diverse applications:

1. High-Temperature Stability

PEI resin excels in high-temperature environments, retaining its mechanical properties and dimensional stability. It has a glass transition temperature (Tg) of up to 217°C and a heat deflection temperature (HDT) of 210°C. PEI can be used continuously at 200°C (392°F) and withstand short-term exposure up to 250°C (482°F).

2. Outstanding Mechanical Properties

PEI is robust, rigid, and wear-resistant, making it ideal for demanding applications. It features high tensile strength (up to 100 MPa), yield strength (85 MPa), and an elastic modulus of 3.2 GPa. Its exceptional rigidity, impact resistance, and dimensional stability at elevated temperatures ensure long-lasting performance, even under challenging conditions.

3. Chemical Resistance

PEI resists a wide range of chemicals, including acids, bases, and organic solvents. It withstands exposure to aromatic hydrocarbons, aliphatic hydrocarbons, chlorinated hydrocarbons, esters, and ketones, making it a reliable choice for applications requiring strong chemical resistance.

4. Exceptional Electrical Properties

PEI resin is highly valued in electronics due to its insulating capabilities and resistance to radiation. It has a low dielectric constant and high dielectric strength, making it ideal for high-frequency and temperature applications. It also offers protection against electronic radiation, making it suitable for environments with nuclear or electronic radiation exposure.

  • Dielectric Strength: 20-30 kV/mm (500-750 V/mil)
  • Volume Resistivity: 10^14-10^15 ohm-cm
  • Surface Resistivity: 10^12-10^13 ohm/square

5. Transparency

PEI offers excellent optical clarity, making it suitable for applications requiring transparent materials. With a light transmittance of up to 90%, PEI is ideal for optical devices, displays, windows, and lenses. It provides both transparency and protection, ensuring visibility without compromising strength.

6. Low Moisture Absorption

PEI’s low moisture absorption ensures that it remains stable under varying humidity conditions. It does not swell or degrade when exposed to moisture, maintaining its physical and mechanical properties, which is crucial for applications requiring consistent performance in humid environments.

7. Flame Resistance

PEI is inherently flame retardant, self-extinguishing once the flame source is removed, and it will not continue to burn. This makes it an excellent choice for applications that demand high flame retardancy, such as electronic device housings, aerospace, and construction materials. It meets stringent flame resistance standards and certifications.

8. Processability

PEI is highly versatile, suitable for injection molding, machining, hot pressing, and extrusion. Despite requiring high processing temperatures, it delivers exceptional dimensional accuracy and surface finishes, ideal for complex, high-precision parts.

What are the properties of PEI?

Property
MetricEnglish
Density0.0500 - 1.90 g/cc0.00181 - 0.0686 lb/inÂł
Filler Content5.00 - 50.0 %5.00 - 50.0 %
Water Absorption0.0150 - 1.30 %0.0150 - 1.30 %
Moisture Absorption at Equilibrium0.000 - 1.30 %0.000 - 1.30 %
Water Absorption at Saturation0.100 - 2.90 %0.100 - 2.90 %
Additive Loading10.0 - 40.0 %10.0 - 40.0 %
Particle Size15.0 µm15.0 µm


Viscosity
3.00 - 87.0 cP
@Temperature 220 - 360 °C
3.00 - 87.0 cP
@Temperature 220 - 360 °C
3.00 - 87.0 cP
@Load 2.16 - 10.0 kg
3.00 - 87.0 cP
@Load 2.16 - 10.0 kg
Maximum Moisture Content0.020.02
Linear Mold Shrinkage0.000 - 0.0230 cm/cm0.000 - 0.0230 in/in
Linear Mold Shrinkage, Transverse0.00100 - 0.0240 cm/cm0.00100 - 0.0240 in/in
Melt Flow1.80 - 113 g/10 min1.80 - 113 g/10 min
Tensile Strength, Ultimate1.00 - 650 MPa145 - 94300 psi
Tensile Strength, Yield20.0 - 255 MPa2900 - 37000 psi
Elongation at Break0.500 - 110 %0.500 - 110 %
Electrical Resistivity0.0500 - 1.00e+18 ohm-cm0.0500 - 1.00e+18 ohm-cm
Surface Resistance1.00 - 5.80e+16 ohm1.00 - 5.80e+16 ohm
Dielectric Constant2.52 - 6.802.52 - 6.80
Dielectric Strength4.33 - 244 kV/mm110 - 6200 kV/in
Transmission, Visible58.0 - 90.0 %58.0 - 90.0 %
Processing Temperature60.0 - 410 °C140 - 770 °F
Nozzle Temperature173 - 421 °C343 - 790 °F
Adapter Temperature270 - 335 °C518 - 635 °F
Die Temperature260 - 360 °C500 - 680 °F
Melt Temperature107 - 427 °C225 - 801 °F
Head Temperature290 - 360 °C554 - 680 °F
Mold Temperature37.8 - 399 °C100 - 750 °F
Drying Temperature60.0 - 152 °C140 - 305 °F
Moisture Content0.0200 - 0.0400 %0.0200 - 0.0400 %
Dew Point-28.9 °C-20.0 °F
Injection Pressure82.7 - 124 MPa12000 - 18000 psi

Comparison of PEI with other high temperature injection molding materials

Polyetherimide (PEI) is often compared to other materials with good-performance like Polyamide 46 (PA46), Liquid Crystal Polymer (LCP), Polyphenylsulfone (PPSU), Polyimide (PI), Polyphthalamide (PPA), and Polyetheretherketone (PEEK). Here’s a detailed comparison of these materials to help you figure out which one is best for your specific application needs.

1. Polyetherimide (PEI)
PEI is a high-performance plastic renowned for its exceptional thermal resistance, functioning reliably at temperatures up to 170°C and withstanding short-term exposure to 200°C. It delivers outstanding mechanical strength, toughness, and excellent electrical insulation. While PEI exhibits good chemical resistance, it is less effective against strong acids and bases. Its durability and thermal stability make it a preferred choice for demanding applications in industries like aerospace, electronics, automotive, and medical devices.
2. Polyetheretherketone (PEEK)

PEEK is another high-temperature material with excellent thermal stability and chemical resistance. However, it is more expensive compared to PEI. PEEK has a slightly higher melting point (343°C vs. 334°C) but offers better impact resistance and more consistent color.

PEEK (polyetheretherketone) is widely used in industries such as aerospace, medical, automotive and electronics, mainly due to its excellent high temperature resistance, corrosion resistance and high strength properties.

3. Polyphenylsulfone (PPSU)

PPSU is a material that performs well at high temperatures, with an operating range of around 180°C, a little higher than PEI. It is tough and strong at high temperatures, but not as strong as PEEK. It is very resistant to water and most chemicals, but may not be as resistant to some chemicals as PEI.

PPSU (polyphenylsulfone) is mainly used in medical devices, beverage bottles and food packaging due to its excellent resistance to high temperature, chemical corrosion and impact.

4. Polyimide (PI)

PI is a high-temperature material with excellent thermal stability and chemical resistance. However, it is more expensive and more difficult to process. While PEI has a lower melting point (334°C) than PI, it has better impact resistance and more consistent color, making it a more convenient choice for many applications.

PI is often used in applications that require extremely high temperatures and high electrical insulation, such as electronic components and aerospace parts.

5. Liquid Crystal Polymer (LCP)

LCP is a high-performance material that can be used for a long time at temperatures up to 250°C, similar to PEI. LCP is stiffer and stronger at high temperatures than PEI. It has similar chemical resistance to PEI, but it may be more resistant to certain chemicals. LCP is used in electronics and high-frequency circuit boards when you need something that is very stiff and stable.

LCP is generally used in electronics, electrical connectors, high-frequency circuit boards and automotive parts.

6. Polyphthalamide (PPA)

PPA offers a long-term use temperature of around 200°C, surpassing PEI’s 170°C. It features excellent tensile strength and wear resistance, often comparable to PEI, with specific advantages under certain conditions. PPA excels in resistance to fats and solvents, while PEI generally performs better against other chemicals. Common applications of PPA include automotive components, electronic devices, and industrial equipment, particularly in scenarios demanding high-temperature stability and robust chemical resistance.

6. Polyphthalamide (PPA)

PPA has a long-term use temperature of about 200°C, higher than PEI’s 170°C. It has good tensile strength and wear resistance, often comparable to PEI but with some advantages in specific conditions. PPA has better solvents and resistance to fats than PEI, although PEI may have better resistance to other chemicals. PPA is used in electronic products, automotive parts, and industrial equipment, especially where high-temperature stability and chemical resistance are important.

8. Advantages of PEI over other high-temperature materials:

â‘  Higher Melting Point

PEI has a higher melting point than many other high-temperature materials, making it ideal for high-temperature processing.

② Improved Impact Resistance

PEI offers superior impact resistance compared to many other high-temperature materials, making it a better choice for parts that might experience impacts or vibrations.

③ More Consistent Color

PEI provides more consistent color compared to many other high-temperature materials, making it a great option when appearance is a priority for your parts.

â‘Ł Enhanced Color Consistency

PEI delivers more consistent color compared to many other high-temperature materials, ensuring your parts look uniform and appealing.

Can PEI be used as injection molding material?

You can certainly use it as injection molding material.
PEI has a high melting point, which can make it tricky to injection mold. But modern injection molding machines and mold designs have come a long way to handle the special needs of PEI.

PEI is a high-performance thermoplastic with outstanding characteristics ideal for injection molding, including:

â‘  Chemical Resistance: PEI resists a wide range of chemicals, making it perfect for use in demanding environments.

② Sterilizability: Its ability to withstand sterilization processes makes PEI a top choice for medical applications.

③ Mechanical Strength: PEI delivers exceptional tensile strength, impact resistance, and modulus for reliable mechanical performance.

④ High Heat Resistance: With a glass transition temperature of approximately 217°C (423°F), PEI excels in high-temperature applications.

⑤ Flame Resistance: PEI’s flame-retardant properties meet UL94 V-0, V-2, and 5VA standards, offering inherent fire safety.

What are the basic conditions for PEI Injection Molding?

PEI is a fantastic plastic known for its ability to handle high temperatures, corrosion, and fatigue. To make high-quality PEI parts, you’ll need to follow these guidelines:

① Mold Temperature: 150-200°C (302-392°F)

Maintain this mold temperature range for optimal part filling and easy ejection.

② Injection Temperature: 350-400°C (662-752°F)

Ensure the injection temperature stays within this range to melt and flow the PEI material correctly.

③ Injection Pressure: 100-200 bar (1450-2900 psi)

Set the injection pressure within this range for proper mold cavity filling and packing.

â‘Ł Injection Speed: 50-100 mm/s (2-4 in/s)

Keep the injection speed in this range to fill and eject the part effectively.

⑤ Cool Time: 10-30 Seconds

Allow the part to cool for the right amount of time to solidify and ensure it maintains its shape and durability.

⑥ Ejection Temperature: 100-150°C (212-302°F)
Ensure the ejection temperature is within this range to allow the part to exit the mold correctly.

⑦ Mold Material: Steel or Aluminum
Select the mold material based on the specific needs of your part and PEI material.

⑧ Cooling System: Proper Cooling Design
Design an efficient cooling system to cool and cure the part effectively, ensuring stability and precision.

⑨ Mold Design: Tailored for Specific Needs
PEI injection molding can create complex shapes, but the mold design should be customized for the part and material.

â‘© Ventilation: Proper Airflow for Ejection
Good ventilation is essential for proper filling and ejection. Ensure vents allow air and gases to escape during injection.

â‘Ş Gate Location: Strategic Placement
Position the gate strategically to ensure smooth filling and efficient mold release.

â‘« Material Selection: Tailored to Requirements
Choose PEI material based on the part’s temperature tolerance, chemical exposure, and strength requirements.

PEI Injection Molding Manufacturing

PEI Injection Molding Manufacturing Guide

How to Perform PEI Injection Molding: A Step-by-Step Guide​

The Polyetherimide, or PEI injection molding process involves several crucial steps to ensure the production of high-quality parts capable of withstanding extreme conditions:

  1. Mold Design:

Create and design the mold, ensuring it includes the appropriate cavities, gates, and runner systems for optimal part production.

  1. Material Selection:

Choose the right PEI material based on the specific needs of your application, considering factors such as temperature resistance, chemical exposure, and required strength.

  1. Material Preparation:

Since PEI is hygroscopic (it absorbs moisture), it must be thoroughly dried before processing to prevent performance degradation. Non-filled grades should be dried at 150°C for about 4 hours, while filled grades may require up to 6 hours.

  1. Machine Setup:a. Temperature Settings: The injection molding machine should be set to high temperatures. The typical melt temperature range for PEI is 350°C to 410°C, while the mold temperature should be between 150°C and 180°C.b. Injection Pressure: Injection pressures typically range from 100 to 200 MPa (700 to 1500 bar), depending on the part design and processing conditions.
  2. Injection Process:a. Injection Speed: To fill the mold quickly, injection speed should be fast. The runner system should be filled in 0.5 to 1.5 seconds, followed by cavity filling in 1 to 5 seconds.b. Holding and Packing: After filling the mold, maintain pressure on the material to ensure complete packing. Hold time will depend on gate size; larger gates require longer hold times.
  3. Cooling:

Allow the PEI material to cool and harden in the mold. The cooling time depends on the wall thickness of the part, with roughly 15 to 20 seconds of cooling time for every tenth of an inch of wall thickness.

  1. Ejection:

After sufficient cooling, eject the part from the mold. The ejection system must be designed carefully to avoid damaging the part.

  1. Post-Processing:

Depending on the application, post-processing steps may include machining, painting, or assembly with other parts to complete the final product.

What are the precautions for PEI Injection Molding?

When performing injection molding with PEI (Polyetherimide), it’s important to pay close attention to several factors due to its high-performance nature. Here are key considerations to ensure a successful molding process:

  1. Select the Appropriate Mold and Injection Molding Machine:

PEI requires high-temperature, high-pressure injection molding machines and molds due to its elevated melting point. For molds, materials like high-speed steel or tungsten carbide are ideal for handling the demands of PEI.

  1. Regulate Injection Speed and Pressure:

Injecting too quickly or with excessive pressure can lead to issues like material breakage or poor flow, which can result in defective parts. It’s essential to adjust the injection speed and pressure according to the type of PEI used and the design of the mold to ensure accurate part formation. Maintaining consistent pressure throughout the process is key to achieving proper mold filling and packing.

  1. Properly Design the Cooling System:

Due to PEI’s high crystallization temperature and thermal conductivity, an efficient cooling system is crucial to reduce crystallinity and prevent thermal stress. Cooling methods like water, air, or gas cooling should be selected based on the specific requirements of your application.

  1. Maintain Dimensional Accuracy and Surface Quality:

The performance of PEI parts heavily depends on their dimensional accuracy and surface quality. Ensure precise control over these factors during production, and address any necessary adjustments to guarantee the final product performs as intended.

  1. Choose the Correct Melt Index:

Different grades of PEI have varying melt index ranges, so it’s essential to select the right one based on your product’s requirements. This ensures optimal performance and appearance of the molded parts.

  1. Proper Drying Treatment:

PEI is highly hygroscopic, meaning it absorbs moisture, which can negatively affect the molding process and material performance. To avoid defects, thoroughly dry PEI pellets in a hot air dryer for at least 4 hours to ensure there’s no moisture that could cause bubbles or weaken the final product.

  1. Control the Processing Temperature:

PEI’s high melting point means you need to set the processing temperature correctly to melt it without degrading the material. A typical processing temperature should be above 360°C, but be cautious not to overheat it, as this can cause color changes or degradation. Maintain precise temperature control during the molding process to ensure proper flow and consistent results. The ideal mold temperature typically ranges from 120°C to 180°C, helping with shrinkage control and improving both the part’s appearance and dimensional accuracy.

  1. Mold Design:

Designing the mold with a good venting system is crucial to prevent the formation of bubbles or burn marks. Since PEI has high flowability, it’s also important to minimize the flow distance and sharp corners in the mold design. This reduces flow stress and prevents cracks, ensuring high-quality parts.

  1. Ensure Proper Ventilation:

Proper ventilation in the mold is essential to prevent air and gases from getting trapped, which can affect the quality of the parts and cause defects.

  1. Control Holding Time:

Holding time is crucial to compensate for material shrinkage after injection. Ensure the pressure is maintained for the right duration to avoid surface defects or dimensional issues due to shrinkage.

  1. Cooling System:

To prevent warping or shrinkage in PEI parts, ensure your cooling system is designed to cool the parts effectively and uniformly. Proper cooling helps maintain the integrity of the part and reduces the risk of deformation during the cooling phase.

  1. Post-Processing:

PEI parts may require post-processing steps like annealing, particularly for thicker or more complex shapes, to relieve internal stresses. Additionally, ensure the part’s surface is free from grease or contaminants before any finishing or bonding operations are carried out to ensure a high-quality result.

  1. Operator Safety:

PEI injection molding involves high temperatures, so operator safety is crucial. Ensure the use of appropriate protective gear, such as heat-resistant gloves and goggles. Also, provide proper ventilation in the workspace to avoid exposure to potentially harmful fumes during the molding process.

What are the advantages of PEI Injection Molding?

Thanks to its high temperature resistance and excellent mechanical properties, PEI injection molding offers several advantages. Here lists several key benefits:

  • Mechanical Properties: PEI is incredibly strong, rigid, and durable. It maintains its shape under high temperatures and, when reinforced with materials like glass or carbon fibers, becomes even more robust and tougher.
  • Environmental Friendliness: PEI utilizes eco-friendly resins that don’t harm the environment when disposed of, making it a sustainable choice for those focused on reducing their environmental impact.
  • Chemical and Radiation Resistance: PEI resists chemicals, radiation, and UV rays, and its performance can be further enhanced with UV stabilizers, making it ideal for use in harsh, demanding environments.
  • Flammability: PEI is naturally flame-resistant, with an oxygen index greater than 4.7 and minimal smoke production. It meets UL94V-0/5V standards, ensuring it won’t ignite easily without the need for additional flame retardants.
  • High Temperature Resistance: With a continuous operating temperature of up to 170°C and heat deflection temperatures between 200°C and 210°C, PEI performs well in high-temperature conditions and can endure short bursts up to 200°C without losing its strength.
  • High-Performance Characteristics: Known for its toughness and rigidity, PEI is an excellent material for precision parts in industries such as automotive and aerospace, where durability is crucial.
  • Processing Efficiency: PEI allows for efficient low-pressure injection molding with short cycle times, improving production speed and reducing costs.
  • Electrical Properties: PEI boasts exceptional electrical insulation properties, offering the highest dielectric strength of any plastic, making it perfect for applications like electrical housings and capacitors.
  • Product Stability and Reliability: PEI products resist water, impact, and electrical leakage, ensuring consistent performance even in humid, low-temperature, or water-exposed conditions.
  • Convenience in Mold Design: PEI doesn’t require complex mold designs, simplifying manufacturing and saving both time and costs in production.
  • Sterilizability: PEI is heat-resistant and can be sterilized in steam autoclaves, making it suitable for medical applications. It also resists gamma radiation, which is commonly used for sterilizing surgical tools and medical devices.
  • Efficiency and Reproducibility: PEI injection molding offers a highly reproducible process that ensures uniform, complex parts with tight tolerances at a lower per-unit cost, ideal for high-volume production.

What are the disadvantages of PEI(Polyetherimide) Injection Molding?

PEI injection molding offers many benefits, but it also comes with some challenges and drawbacks. Here are a few things to consider:

  • Long Lead Time: Creating PEI injection molds takes a significant amount of time, often 5 to 7 weeks just for the mold itself, followed by another 2 to 4 weeks to produce the parts and deliver them. This extended timeline can be a challenge when fast turnaround is needed.
  • High Initial Mold Cost: The cost of molds for PEI injection molding can be quite high, particularly for complex designs. Simple molds can range from $2,000 to $5,000, but more intricate parts can drive the cost even higher. As a result, this process is often not cost-effective for producing small quantities of parts due to the expensive upfront mold investment.
  • Design Change Limitations: Making design changes during the molding process can be both costly and time-consuming. Altering part designs often requires mold modifications, which adds significant expenses and delays—making it difficult for industries that require frequent design iterations or rapid prototyping.
  • Specialized Equipment: PEI requires high-quality injection molding machines and molds that can withstand high temperatures and precision. These specialized tools can be expensive, adding to the overall cost of production.
  • Material Cost: As a high-performance material, PEI is typically more expensive than other thermoplastics. This increased material cost can make it less appealing for cost-sensitive applications, particularly in small batch production. Additionally, PEI is not as widely available as other materials, making it harder to source from suppliers.
  • Processing Challenges: To avoid defects, PEI must be processed under specific conditions. It needs thorough drying before use, and its high melting point demands specialized processing parameters, including high temperatures (350°C to 410°C) and high pressures (70 to 150 MPa). Failing to manage these parameters properly can lead to defects or inconsistent product quality.
  • Design Constraints: Injection molding comes with design limitations. Complex shapes may require additional design modifications or the creation of multiple parts, which increases manufacturing complexity and costs.

What are the Applications of PEI Injection Molding?

PEI injection molding is a versatile process used across various high-end industries, thanks to PEI’s exceptional properties such as temperature stability, mechanical strength, and chemical resistance. Common applications include:

  • Medical: PEI’s biocompatibility and resistance to high temperatures and chemicals make it perfect for medical devices, such as implantable devices, surgical tools, medical instrument housings, and diagnostic components.
  • Aerospace: PEI’s ability to maintain stable performance in extreme conditions makes it ideal for aerospace applications, including aircraft parts, satellite components, and spacecraft components.
  • Electronics: With its excellent electrical insulation and chemical resistance, PEI is used in electronics for parts like connectors, switches, electrical insulators, and circuit boards, ensuring high performance and stability.
  • Industrial: PEI’s wear and chemical resistance make it suitable for industrial components like pumps, valves, seals, and gears, ensuring long-lasting durability in challenging environments.
  • Automotive: PEI’s high heat resistance and strength are perfect for automotive applications that need to withstand high temperatures and stress, such as dashboard components, engine parts, ECUs, transmission components, and interior parts.
  • Energy: PEI is also used in the energy industry for parts like wind turbine components, solar panel components, and nuclear reactor parts, providing reliability and durability in energy applications.
  • Consumer Goods: PEI injection molding is used to create durable parts for consumer goods.
  • Optical Devices: Due to its high temperature stability and mechanical strength, PEI is used in optical devices and military applications, including structural components, protective covers, and optical instruments.
  • Marine: PEI injection molding is ideal for marine industry components, including parts for ships, boats, and offshore platforms, offering durability and resistance to harsh conditions.
  • Food Industry: PEI’s heat resistance and chemical stability make it perfect for food industry applications, such as food processing equipment parts, containers, and packaging, ensuring hygiene and resistance to chemicals.
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